Studies on the Powerful Photoluminescence of the Lu₂O₃:Eu³⁺ System in the Form of Ceramic Powders and Crystallized Aerogels

Abstract

This study compared the chemical, structural, and luminescent properties of xerogel-based ceramic powders (CPs) with those of a new series of crystallized aerogels (CAs) synthesized by the epoxy-assisted sol–gel process. Materials with different proportions of Eu3+ (2, 5, 8, and 10 mol%) were synthesized in Lu2O3 host matrices, as well as a Eu2O3 matrix for comparative purposes. The products were analyzed by infrared spectroscopy (IR), X-ray diffraction (XRD), scanning electron microscopy (SEM) with energy-dispersive spectroscopy (EDS), transmission electron microscopy (TEM), photoluminescence analysis, and by the Brunauer–Emmett–Teller (BET) technique. The results show a band associated with the M-O bond, located at around 575 cm−1. XRD enabled us to check two ensembles: matrices (Lu2O3 or Eu2O3) and doping (Lu2O3:Eu3+) with appropriate chemical compositions featuring C-type crystal structures and intense reflections by the (222) plane, with an interplanar distance of around 0.3 nm. Also, the porous morphology presented by the materials consisted of interconnected particles that formed three-dimensional networks. Finally, emission bands due to the energy transitions (5DJ, where J = 0, 1, 2, and 3) were caused by the Eu3+ ions. The samples doped at 10 mol% showed orange-pink photoluminescence and had the longest disintegration times and greatest quantum yields with respect to the crystallized Eu2O3 aerogel.

Keywords

• rare earths
• aerogel
• photoluminescence