SEBS-Grafted Itaconic Acid as Compatibilizer for Elastomer Nanocomposites Based on BaTiO₃ Particles

Abstract

Itaconic acid (IA) is an organic acid produced by the fermentation of sugars with aspergillus. It has been identified as one of the top 12 building-block chemicals. Here, we report the use of IA as a possible substitute to petroleum-based compatibilizers in polymer composite. We applied this study to thermoplastic elastomers based on styrene copolymers, since they are commonly used in blends and composites. Poly(styrene-b-ethylene-butylene-b-styrene) (SEBS) was grafted with 2.6 wt.% of itaconic acid (SEBS-g-IA) prepared by a reactive melt-mixing process, and was subsequently used to prepare composites filled with BaTiO3.). IA was successfully grafted as demonstrated by FTIR and XRD. SEBS-g-IA composites presented better mechanical properties, achieving an increase of Young modulus up to 80% compared with the neat polymer. This was ascribed to better dispersion and compatibility with the filler. Additionally, SEBS-g-IA showed increased dielectric permittivity, i.e., showed increased polarity, which indicates that it could potentially be used as a modifier for specialized polymers.

Keywords

• thermoplastic elastomer
• barium titanate nanoparticles
• compatibilizer