Тонкие химические технологии (Aug 2009)

Studying of the conjugate catalytics degidration of methanol to formaldehyde in the presence of hydrogen peroxide

  • V. F. Tretyakov,
  • A. M. Ilolov,
  • N. A. Frantsuzova,
  • R. M. Talyshinsk

Journal volume & issue
Vol. 4, no. 4
pp. 60 – 70

Abstract

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From the studies of the kinetics of methanol conjugate dehydration process, a kinetic model has been proposed and kinetic parameters calculated. It was discovered that when other substances like ethane, ethylene were used as initiators the catalyst surface coked rapidly. On the K-1 model in the presence of hydrogen peroxide (1% in water solution of the initial methanol) the temperature of the dehydration process reduces by 50-60ºС at 50% formaldehyde yield and allows for the reaction to be carried out at a temperature of 820-830ºС

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