Influence of SiO₂ Embedding on the Structure, Morphology, Thermal, and Magnetic Properties of Co_0.4Zn_0.4Ni_0.2Fe₂O₄ Particles

Abstract

(Co0.4Zn0.4Ni0.2Fe2O4)α(SiO2)(100−α) samples obtained by embedding Co0.4Zn0.4Ni0.2Fe2O4 nanoparticles in SiO2 in various proportions were synthesized by sol-gel process and characterized using thermal analysis, Fourier-transform infrared spectroscopy, X-ray diffraction, transmission electron microscopy, inductively coupled plasma optical emission spectrometry, and magnetic measurements. Poorly crystalline Co–Zn–Ni ferrite at low annealing temperatures (500 °C) and highly crystalline Co–Zn–Ni ferrite together with traces of crystalline Fe2SiO4 (800 °C) and SiO2 (tridymite and cristobalite) (1200 °C) were obtained. At 1200 °C, large spherical particles with size increasing with the ferrite content (36–120 nm) were obtained. Specific surface area increased with the SiO2 content and decreased with the annealing temperature above 500 °C. Magnetic properties were enhanced with the increase in ferrite content and annealing temperature.

Keywords

• Co_0.4Zn_0.4Ni_0.2Fe₂O₄
• silica matrix
• crystalline phase
• annealing temperature
• magnetic behavior