First detection of industrial hydrogen emissions using high precision mobile measurements in ambient air

Abstract

Abstract Projections towards 2050 of the global hydrogen (H2) demand indicate an eight-fold increase in present-day hydrogen consumption. Leakage during production, transport, and consumption therefore presents a large potential for increases in the atmospheric hydrogen burden. Although not a greenhouse gas itself, hydrogen has important indirect climate effects, and the Global Warming Potential of H2 is estimated to be 12.8 times that of CO2. Available technologies to detect hydrogen emissions have been targeted at risk mitigation of industrial facilities, while smaller climate-relevant emissions remain undetected. The latter requires measurement capacity at the parts-per-billion level (ppb). We developed and demonstrated an effective method to detect small hydrogen emissions from industrial installations that combines active AirCore sampling with ppb-precision analysis by gas chromatography. We applied our methodology at a chemical park in the province of Groningen, the Netherlands, where several hydrogen production and storage facilities are concentrated. From a car and an unmanned aerial vehicle, we detected and quantified for the first time small but persistent industrial emissions from leakage and purging across the hydrogen value chain, which include electrolysers, a hydrogen fuelling station, and chemical production plants. Our emission estimates indicate current loss rates up to 4.2% of the estimated production and storage in these facilities. This is sufficiently large to urgently flag the need for monitoring and verification of H2 emissions for the purpose of understanding our climate change trajectory in the 21st century.