Parametric investigation and RSM optimization of DBD plasma methods (direct & indirect) for H2S conversion in the air

Abstract

Hydrogen sulfide (H2S) is known as a harmful pollutant for the environment and human health, and its emission control is a high priority. Non-thermal plasma is an effective technology in this field. In this study, for the first time, the performance of direct and indirect H2S plasma conversion methods was compared, optimized, and modeled with the CCD method. H2S was diluted in zero air, and the study investigated the effect of discharge power, relative humidity, total flow rate, initial H2S concentration, and their interactions. ANOVA results showed that the models for H2S conversion efficiency and energy yield were significant and efficient. The direct method achieved a maximum conversion efficiency of 56 % and energy yield of 3.43 g/kWh, while the indirect method produced 68 % conversion efficiency and 1.59 g/kWh energy yield. According to the process optimization results, the direct conversion method is more optimal than the indirect conversion method due to the presence of active species and high-energy electrons in the plasma treatment, and it is a better choice if there are suitable working conditions.

Keywords

• H2S conversion
• Response surface methodology
• Dielectric barrier discharge
• Non-thermal plasma
• Ozone
• Process optimization