Nature Communications (Feb 2020)
Elucidating the mechanism of heterogeneous Wacker oxidation over Pd-Cu/zeolite Y by transient XAS
Abstract
Unlike the homogeneous Wacker process, understanding of the mechanism of the heterogeneous system remains superficial. Here, the authors investigate the mechanism of heterogeneous Wacker oxidation over Pd-Cu/zeolite Y through the synergistic combination of kinetic, spectroscopic and chemometric studies.