npj Materials Degradation (Aug 2023)

Study on the oxidation resistance mechanism of self-healable NiAl coating deposited by atmospheric plasma spraying

  • Li Zhang,
  • Di Wang,
  • Xian-Jin Liao,
  • Rui Chen,
  • Xiao-Tao Luo,
  • Chang-Jiu Li

DOI
https://doi.org/10.1038/s41529-023-00383-0
Journal volume & issue
Vol. 7, no. 1
pp. 1 – 11

Abstract

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Abstract A dense NiAl coating with low oxide content was deposited on the GH4202 superalloy substrate by atmospheric plasma spraying (APS) using carbon-containing Ni/Al composite powders. Compared with traditional APS NiAl coatings with high oxide content, this coating exhibits better long-term oxidation resistance at 900 °C in air. For the NiAl coating with low oxide content, it was found that the improved inter-splat bonding, due to limited oxide inclusions, promotes the formation of a continuous protective Al2O3 layer on the coating surface during oxidation. During long-term oxidation, the dispersion of oxide scales within the coating and element diffusion across splats result in the in-situ healing of unbonded inter-splat interfaces.