The Preparation of High-Performance MoO₃ Nanorods for 2.1 V Aqueous Asymmetric Supercapacitor

Abstract

In order to broaden the working voltage (1.23 V) of aqueous supercapacitors, a high-performance asymmetric supercapacitor with a working voltage window reaching up to 2.1 V is assembled using a nanorod-shaped molybdenum trioxide (MoO3) negative electrode and an activated carbon (AC) positive electrode, as well as a sodium sulfate–ethylene glycol ((Na2SO4-EG) electrolyte. MoO3 electrode materials are fabricated by adjusting the hydrothermal temperature, hydrothermal time and solution’s pH value. The specific capacity of the optimal MoO3 electrode material can reach as high as 244.35 F g−1 at a current density of 0.5 A g−1. For the assembled MoO3//AC asymmetric supercapacitor with a voltage window of 2.1 V, its specific capacity, the energy density, and the power density are 13.52 F g−1, 8.28 Wh kg−1, and 382.15 W kg−1 at 0.5 A g−1, respectively. Moreover, after 5000 charge–discharge cycles, the capacity retention rate of the device still reaches 109.2%. This is mainly attributed to the small particle size of MoO3 nanorods, which can expose more electrochemically active sites, thus greatly facilitating the transport of electrolyte ions, immersion at the electrolyte/electrolyte interface and the occurrence of electrochemical reactions.

Keywords

• aqueous electrolyte
• MoO₃
• wide voltage window
• supercapacitor
• hydrothermal method