Near-threshold photoelectron angular distributions from two-photon resonant photoionization of He

Abstract

Two-photon resonant photoionization of helium is investigated both experimentally and theoretically. Ground state helium atoms are excited to the 1s4p, 1s5p and 1s6p ^1 P states by synchrotron radiation and ionized by a synchronized infrared pulsed picosecond laser. The photoelectron angular distributions of the emitted electrons are measured using a velocity map imaging (VMI) spectrometer. The measured asymmetry parameters of the angular distribution allow the phase differences and the ratios of the dipole matrix elements of the 1s ϵ s and 1s ϵ d channels to be determined. The experimental results agree with the calculated values obtained in a configuration–interaction calculation with a Coulomb–Sturmian basis set. The effects of the radiative decay of the intermediate state and the static electric field of the VMI spectrometer on the measurements are discussed.