Tetracycline Adsorption Performance and Mechanism Using Calcium Hydroxide-Modified Biochars
Kaifeng Wang,
Runlin Yao,
Dongqing Zhang,
Na Peng,
Ping Zhao,
Yongming Zhong,
Haijun Zhou,
Jiahui Huang,
Chen Liu
Affiliations
Kaifeng Wang
Guangdong Provincial Key Laboratory of Petrochemical Pollution Process and Control, Key Laboratory of Petrochemical Pollution Control of Guangdong Higher Education Institutes, School of Environmental Science and Engineering, Guangdong University of Petrochemical Technology, Maoming 525000, China
Runlin Yao
Bathurst Future Agri-Tech Institute, Qingdao Agricultural University, Qingdao 266109, China
Dongqing Zhang
Guangdong Provincial Key Laboratory of Petrochemical Pollution Process and Control, Key Laboratory of Petrochemical Pollution Control of Guangdong Higher Education Institutes, School of Environmental Science and Engineering, Guangdong University of Petrochemical Technology, Maoming 525000, China
Na Peng
Guangdong Provincial Key Laboratory of Petrochemical Pollution Process and Control, Key Laboratory of Petrochemical Pollution Control of Guangdong Higher Education Institutes, School of Environmental Science and Engineering, Guangdong University of Petrochemical Technology, Maoming 525000, China
Ping Zhao
Geological Party 105, Guizhou Provincial Bureau of Geology and Mineral Exploration and Development, Guiyang 550018, China
Yongming Zhong
Guangdong Provincial Key Laboratory of Petrochemical Pollution Process and Control, Key Laboratory of Petrochemical Pollution Control of Guangdong Higher Education Institutes, School of Environmental Science and Engineering, Guangdong University of Petrochemical Technology, Maoming 525000, China
Haijun Zhou
Guangdong Provincial Key Laboratory of Petrochemical Pollution Process and Control, Key Laboratory of Petrochemical Pollution Control of Guangdong Higher Education Institutes, School of Environmental Science and Engineering, Guangdong University of Petrochemical Technology, Maoming 525000, China
Jiahui Huang
Guangdong Provincial Key Laboratory of Petrochemical Pollution Process and Control, Key Laboratory of Petrochemical Pollution Control of Guangdong Higher Education Institutes, School of Environmental Science and Engineering, Guangdong University of Petrochemical Technology, Maoming 525000, China
Chen Liu
Guangdong Provincial Key Laboratory of Petrochemical Pollution Process and Control, Key Laboratory of Petrochemical Pollution Control of Guangdong Higher Education Institutes, School of Environmental Science and Engineering, Guangdong University of Petrochemical Technology, Maoming 525000, China
Tetracycline is frequently found in various environments and poses significant ecological risks. Calcium hydroxide-modified biochar has shown potential as a material for removing multiple classes of pollutants from wastewater streams. The tetracycline-adsorption performance and mechanism of alkali-modified biochars derived from nine wastes (corn straw, rice straw, swine manure, cypress powder, wheat straw, peanut shell, walnut shell powder, soybean straw, and corncobs) were investigated in the study. Among the four alkalis tested, calcium hydroxide exhibited the most effective modification effects at a pyrolysis temperature of 500 °C. Straw biomass was most suitable to be modified by calcium hydroxide, and calcium hydroxide-modified biochar showed the highest adsorption performance for tetracycline. The maximum adsorption capacities were 8.22 mg g−1 for pristine corn straw biochar and 93.46 mg g−1 for calcium hydroxide-modified corn straw biochar. The tetracycline adsorption mechanism by calcium hydroxide-modified corn straw biochar involved hydrogen bonding, oxygen-containing functional groups, Ca2+ metal complexation, and electrostatic attraction. Consequently, calcium hydroxide-modified corn straw biochar emerges as an environment-friendly, cost-effective, and efficient tetracycline adsorbent.
