Role of Small Addition of Sc and Zr in Clustering and Precipitation Phenomena Induced in AA7075

Abstract

A detailed characterization of phase transformations in the heat-treated commercial 7075 aluminum alloys without/with low Sc–Zr addition was carried out. Mechanical and electrical properties, thermal and corrosion behavior were compared to the microstructure development. The eutectic phase consists of four parts: MgZn2 phase, Al2CuMg phase (S-phase), Al2Zn3Mg3 phase (T-phase), and primary λ-Al(Mn,Fe,Si) phase. Strengthening during non-isothermal (isochronal) annealing is caused by a combination of formation of the GP zones, η’-phase, T-phase and co-presence of the primary and secondary Al3(Sc,Zr)-phase particles. Positive influence on corrosion properties is owing to the addition of Sc–Zr. Positron annihilation showed an evolution of solute Zn,Mg-(co-)clusters into (precursors of) the GP zones in the course of natural ageing. The concentration of the (co-)clusters is slightly negatively affected by the low Sc–Zr addition. A combination of both precipitation sequences of the Al–Zn–Mg–Cu-based system was observed. The apparent activation energy values for dissolution/formation of the clusters/GP zones and for formation of the metastable η’-phase, stable T-phase and stable η-phase were calculated.

Keywords

• 7xxx aluminum series
• early precipitation stages
• corrosion
• Al₃(Sc,Zr) particles
• annihilation of positrons
• activation energy