Effect of Plasma Nitriding and Oxidation on the Corrosion Resistance of 304 Stainless Steel in LiBr/H₂O and CaCl₂-LiBr-LiNO₃-H₂O Mixtures

Abstract

The effect of plasma nitriding and oxidation on the corrosion resistance of AISI 304 type stainless steel in LiBr/H2O and CaCl2-LiBr-LiNO3-H2O mixtures at 80 °C has been evaluated by using potentiodynamic polarization curves and electrochemical impedance spectroscopy techniques (EIS). Steel was plasma treated at 500 °C during 8 h under different atmospheres, nominally 20% N2 + 80% H2, 100% N2 and 100% O2. X-ray diffraction analysis (XRD) showed the presence of a CrN layer in nitrided specimens, whereas scanning electronic microscopy analysis revealed that specimen treated in the 20% N2 + 80% H2 atmosphere showed the thickest nitride layer. Specimens nitrided in the 20% N2 + 80% H2 atmosphere had the noblest open circuit potential value in both solutions, whereas potentiodynamic polarization curves indicated the formation of a passive layer. These specimens exhibited the lowest corrosion and passivation current density values. Corrosion process was under charge transfer control in both solutions regardless of the plasma treatment. The type of corrosion suffered by the steel under all treatments was the pitting type of corrosion. Pits density was the lowest for nitrides steels rather than that for untreated or pre-oxidized ones.

Keywords

• plasma nitriding
• pre-oxidation
• stainless steel
• LiBr
• corrosion