Acta Crystallographica Section E (Aug 2010)

1-Benzoyl-3,3-bis(propan-2-yl)thiourea

  • N. Gunasekaran,
  • R. Karvembu,
  • Seik Weng Ng,
  • Edward R. T. Tiekink

DOI
https://doi.org/10.1107/S1600536810028862
Journal volume & issue
Vol. 66, no. 8
pp. o2113 – o2113

Abstract

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Two independent thiourea derivatives comprise the asymmetric unit of the title compound, C14H20N2OS. The major difference between the molecules relates to a twist in the relative orientation of the benzene rings [torsion angles = 4.5 (2) and −19.9 (2)° for the two independent molecules]. The thiocarbonyl and carbonyl groups lie to opposite sides of the molecule as there are twists about the central N—S bond [torsion angles = 83.90 (15) and 81.77 (15)°]. Supramolecular chains extending parallel to [101] with a stepped topology and mediated by N—H...O hydrogen bonding feature in the crystal structure. C—H...O and C—H...π interactions are also present.