Surface Organic Modification of CaCO3-TiO2 Composite Pigment

Sijia Sun; Hao Ding; Yanpeng Zha; Wanting Chen; Zhuoqun Xu

doi:10.3390/min9020112

Minerals (Feb 2019)

Surface Organic Modification of CaCO3-TiO2 Composite Pigment

Sijia Sun,
Hao Ding,
Yanpeng Zha,
Wanting Chen,
Zhuoqun Xu

Affiliations

Sijia Sun: Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes, National Laboratory of Mineral Materials, School of Materials Science and Technology, China University of Geosciences, Beijing 100083, China
Hao Ding: Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes, National Laboratory of Mineral Materials, School of Materials Science and Technology, China University of Geosciences, Beijing 100083, China
Yanpeng Zha: Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes, National Laboratory of Mineral Materials, School of Materials Science and Technology, China University of Geosciences, Beijing 100083, China
Wanting Chen: Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes, National Laboratory of Mineral Materials, School of Materials Science and Technology, China University of Geosciences, Beijing 100083, China
Zhuoqun Xu: Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes, National Laboratory of Mineral Materials, School of Materials Science and Technology, China University of Geosciences, Beijing 100083, China

DOI: https://doi.org/10.3390/min9020112
Journal volume & issue: Vol. 9, no. 2
p. 112

Abstract

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To improve the properties and dispersibility of CaCO3-TiO2 composite pigments (CaCO3-TiO2) in organic matrices, the surface modification of CaCO3-TiO2 was performed with sodium stearate (SS) as an organic modifier by wet ultra-fine grinding in a stirred mill. The pigment properties of modified CaCO3-TiO2 and its dispersibility in organic media were tested and characterized. The binding mechanism between CaCO3-TiO2 and SS was explored by infrared spectrometry (IR) and X-ray photoelectron energy spectroscopy (XPS). The results showed that the mechanical grinding strength and SS dosage had a significant effect on the activation index and sedimentation rate of CaCO3-TiO2. After surface modification, the surface of CaCO3-TiO2 turned from a hydrophilic surface to a hydrophobic surface and the surface free energy was reduced. In addition, the hiding property and dispersibility of CaCO3-TiO2 in the organic medium were significantly improved. IR and XPS results indicated that the modifier SS was adsorbed on the surface of CaCO3-TiO2 by chemical combination.

Published in Minerals

ISSN: 2075-163X (Online)
Publisher: MDPI AG
Country of publisher: Switzerland
LCC subjects: Science: Geology: Mineralogy
Website: https://www.mdpi.com/journal/minerals

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