Biomass-Derived Porous Carbon Materials for Li-Ion Battery

Abstract

Biomass-based carbon nanofibers (CNF) were synthesized using lignin extracted from sawdust and polyacrylonitrile (PAN) (30:70) with the help of the electrospinning method and subsequent stabilization at 220 °C and carbonization at 800, 900, and 1000 °C. The synthesized CNFs were studied by scanning electron microscopy, energy-dispersive X-ray analysis, Raman spectroscopy, and the Brunauer–Emmett–Teller method. The temperature effect shows that CNF carbonized at 800 °C has excellent stability at different current densities and high capacitance. CNF 800 in the first test cycle at a current density of 100 mA/g shows an initial capacity of 798 mAh/g and an initial coulomb efficiency of 69.5%. The CNF 900 and 1000 show an initial capacity of 668 mAh/g and 594 mAh/g, and an initial Coulomb efficiency of 52% and 51%. With a long cycle (for 500 cycles), all three samples at a current density of 500 mA/g show stable cycling in different capacities (CNF 800 in the region of 300–400 mAh/g, CNF 900 and 1000 in the region of 100–200 mAh/g).

Keywords

• sawdust
• electrospinning
• fibers
• anode
• battery