Fe3O4@C core-shell nanoparticles as adsorbent of ionic zinc: evaluating of the adsorptive capacity

Abstract

Zinc is an important chemical element in many metabolic mechanisms at low concentrations, but can be toxic when administrated in doses higher than 500 µg·g-1 or 3 mg·L-1. This metal has been detected in many aquatic environments due to several industry activities and swine manure effluents. Thus, the contaminant removal of water and wastewater has been a major challenge. Many processes are applied and evaluated in an attempt to removal zinc found in environment, such as adsorption. In the present study Fe3O4@C core-shell nanoparticles were synthesized and used to adsorb ionic zinc species in aqueous solutions. The core-shell nanoparticles exhibited excellent zinc removal capacity, with a maximum efficiency equal 65% where applied in an aqueous solution containing 10 mg·l-1 of this ionic metal.

Keywords

• Core-shell nanoparticles
• adsorption of zinc
• adsorption by magnetite-carbon core-shell nanoparticles