Laser beam powder bed fusion of novel biomedical titanium/niobium/tantalum alloys: Powder synthesis, microstructure evolution and mechanical properties

Abstract

The synthesis of spherical titanium/niobium/tantalum (TNT) alloy powders, namely Ti-20Nb-6Ta, Ti-27Nb-6Ta, Ti-35Nb-6Ta, and Ti-22Nb-19Ta (in wt-%) by electrode induction melting gas atomization is reported. The powder materials are characterized in detail using X-ray diffraction and scanning electron microscopy. Their processability via laser beam powder bed fusion (PBF-LB/M) is proven, and microstructure as well as mechanical properties of the additively manufactured specimens are assessed. All powders feature a dendrite-type microstructure with Nb/Ta-rich dendritic and Ti-rich inter-dendritic phases. Crystal structures of the powders are strongly composition-dependent. Nb- and Ta-rich Ti-35Nb-6Ta and Ti-22Nb-19Ta feature a body-centered cubic lattice, whereas Ti-rich Ti-20Nb-6Ta and Ti-27Nb-6Ta powders are characterized by multi-phase microstructures, consisting of non-equilibrium martensitic phases. Processing by PBF-LB/M causes significant changes in their microstructures: the dendrite-type morphologies vanish, and the formation of microstructures with a homogeneous element distribution can be observed in all additively manufactured parts. Ultimate tensile strength (UTS) as well as elongation at fracture are assessed by tensile testing. UTS values are found to be in a range from 651 MPa (Ti-35Nb-6Ta) to 802 MPa (Ti-20Nb-6Ta); strain-to-failure is between 21.3 % (Ti-35Nb-6Ta) and 31.7 % (Ti-22Nb-19Ta). Ductile fracture behavior is seen for all TNT alloys investigated.

Keywords

• Electrode induction melting gas atomization (EIGA)
• Laser beam powder bed fusion (PBF-LB/M)
• Biomedical alloys
• Pre-alloyed refractory metal powder