Acta Crystallographica Section E (May 2010)

Aqua(1,10-phenanthroline-κ2N,N′)(dl-threoninato-κ2N,O1)copper(II) chloride dihydrate

  • Yi-Han Tan,
  • Siang-Guan Teoh,
  • Kei-Lin Sek,
  • Wan-Sin Loh,
  • Hoong-Kun Fun

DOI
https://doi.org/10.1107/S1600536810015278
Journal volume & issue
Vol. 66, no. 5
pp. m595 – m596

Abstract

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The asymmetric unit of the title compound, [Cu(C4H8NO3)(C12H8N2)(H2O)]Cl·2H2O, contains a complex cation, a chloride anion and two water molecules. The CuII ion has a distorted square-pyramidal coordination geometry formed by one bidentate phenanthroline ligand, one O,N-bidentate dl-threoninate ligand and one apical water molecule. In the crystal structure, intermolecular O—H...O, N—H...O, N—H...Cl and O—H...Cl hydrogen bonds link the components into layers. A single weak intermolecular C—H...O interaction connects these layers into a three-dimensional network.