Preparation and characterization of acetate cellulose electrospun nanofibers membrane: Potential application on wastewater treatment

Abstract

Development of nanofiber membranes with the ability to remove organic dye such as Indigo Carmine (IC) from effluent wastewater is of immense help to the textile industry. In the present study, we investigate the preparation of cellulose acetate (CA) nanofiber membranes with optimized performances using electrospinning technique for effective removal of Indigo Carmine (IC) dye. Electrospinning parameters and solvent system containing acetic acid were adjusted to obtain CA nanofibers membranes which better suits dye removal application. The obtained nanofiber membranes were characterized using Scanning Electron Microscopy (SEM), Fourier-Transform Infrared Spectroscopy (FT-IR) and contact angle analysis. Results show that nanofiber webs with optimized electrospinning parameters were continuously formed and are substantially free of defects such as beading, with an average diameter of 950 ± 50 nm. Hydrophobicity of membranes were successfully modified and showed important increase of contact angle values from 37° to 107°. The stirring time was varied to improve the solution homogeneity and consequently the response of membranes in filtration treatment. The CA membranes performance was evaluated through water flux and permeability measurement and tested on IC dye removal. The results showed a rate of dye removal around 83 % and a maximum adsorption capacity (Qm) of 13.09 mg/g for the optimized CA membranes.

Keywords

• Electrospinning
• Nanofibers
• Hydrophobicity
• Indigo carmine
• Nanofiltration