Acta Crystallographica Section E (Aug 2010)

catena-Poly[[(nitrato-κ2O,O′)silver(I)]-μ-N,N′-bis(3-pyridylmethylidene)benzene-1,4-diamine]

  • Yong-Hao Liu,
  • Quan Xu,
  • Zhi-You Han

DOI
https://doi.org/10.1107/S1600536810025997
Journal volume & issue
Vol. 66, no. 8
pp. m903 – m903

Abstract

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In the title compound, [Ag(NO3)(C18H14N4)]n, the AgI atom is coordinated by two N atoms from two N,N′-bis(3-pyridylmethylidene)benzene-1,4-diamine (bpbd) molecules and two O atoms from a bidentate nitrate anion. The bpbd molecules bridge the Ag atoms into a chain. Two adjacent chains are further connected by Ag...Ag interactions [3.1631 (8) Å], forming a double-chain structure. A π–π interaction [centroid–centroid distance = 3.758 (3) Å] occurs between the double chains. Interchain C—H...O hydrogen bonds are observed.