Zn(II) Three-Dimensional Metal-Organic Frameworks Based on 2,5-Diiodoterephthalate and N,N Linkers: Structures and Features of Sorption Behavior

Alexander S. Zaguzin; Taisiya Sukhikh; Maxim N. Sokolov; Vladimir P. Fedin; Sergey A. Adonin

doi:10.3390/inorganics11050192

Inorganics (Apr 2023)

Zn(II) Three-Dimensional Metal-Organic Frameworks Based on 2,5-Diiodoterephthalate and N,N Linkers: Structures and Features of Sorption Behavior

Alexander S. Zaguzin,
Taisiya Sukhikh,
Maxim N. Sokolov,
Vladimir P. Fedin,
Sergey A. Adonin

Affiliations

Alexander S. Zaguzin: Nikolaev Institute of Inorganic Chemistry SB RAS, 630090 Novosibirsk, Russia
Taisiya Sukhikh: Nikolaev Institute of Inorganic Chemistry SB RAS, 630090 Novosibirsk, Russia
Maxim N. Sokolov: Nikolaev Institute of Inorganic Chemistry SB RAS, 630090 Novosibirsk, Russia
Vladimir P. Fedin: Nikolaev Institute of Inorganic Chemistry SB RAS, 630090 Novosibirsk, Russia
Sergey A. Adonin: Nikolaev Institute of Inorganic Chemistry SB RAS, 630090 Novosibirsk, Russia

DOI: https://doi.org/10.3390/inorganics11050192
Journal volume & issue: Vol. 11, no. 5
p. 192

Abstract

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Two new coordination polymers based on Zn(II) and 2,5-diiodoterephthalate—{[Zn(2,5-I-bdc)bpe}] (1) and {[Zn(2,5-I-bdc)bpen}] (2)—were synthesized and characterized. Polymers 1 and 2 feature halogen bonding between the I atoms of MOF and DMF guest molecules, which plays a crucial role in structure stabilization. Selectivity of sorption towards different organic substrates was examined.

Published in Inorganics

ISSN: 2304-6740 (Online)
Publisher: MDPI AG
Country of publisher: Switzerland
LCC subjects: Science: Chemistry: Inorganic chemistry
Website: http://www.mdpi.com/journal/Inorganics

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