Bicarbonate-Activated Hydrogen Peroxide for an Azo Dye Degradation: Experimental Design

Abstract

The present study investigated the degradation of an aqueous Allura Red AC (AR–AC) solution by activating hydrogen peroxide with bicarbonate using cobalt ion (Co2+) as the catalyst. Four independent variables (H2O2, NaHCO3, Co2+, and dye concentrations) were analyzed in the composite central design (CCD). AR–AC degradation was optimized using the response surface methodology (RSM). Under optimal degradation conditions (41.86 mg/L AR–AC, 5.58 mM H2O2, 2.00 mM NaHCO3, and 9.00 µM Co2+), decolorization > 99.86%, mineralization (CO2 to conversion) of 12.99%, and total nitrogen removal of 51.97% were achieved. The predicted values for the three response variables were consistent with the experimental values, with determination coefficients (R2) greater than 0.9053. Because cobalt ions (Co2+) are a source of water pollution, after oxidation, these were adsorbed on sodium bentonite (Na–Bent), obtaining a final concentration of <0.01 mg/L. Bicarbonate-activated hydrogen peroxide is a potential technology for dye wastewater treatment that operates at an alkaline pH and at ambient temperature.

Keywords

• bicarbonate-activated peroxide
• azo-dye
• Allura Red AC
• cobalt
• experimental design
• degradation