Acta Crystallographica Section E (Nov 2009)

Chloridotetrakis(pyridine-4-carbaldehyde-κN)copper(II) chloride

  • Xiu-Jin Meng,
  • Shu-Hua Zhang,
  • Ge-Ge Yang,
  • Xue-Ren Huang,
  • Yi-Min Jiang

DOI
https://doi.org/10.1107/S1600536809041816
Journal volume & issue
Vol. 65, no. 11
pp. m1380 – m1380

Abstract

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In the molecular structure of the title compound, [CuCl(C6H5NO)4]Cl, the CuII atom is coordinated by four N atoms of four pyridine-4-carboxaldehyde ligands and one chloride anion in a slightly distorted square-pyramidal coordination geometry. There is also a non-coordinating Cl− anion in the crystal structure. The CuII atom and both Cl atoms are situated on fourfold rotation axes. A weak C—H...Cl interaction is also present.