Supercapacitor Performance of MXene-Coated Carbon Nanofiber Electrodes

Abstract

MXenes consisting of thin layers of transition metal carbides or nitrides are good candidates for electrode materials due to their excellent electrical conductivity and fast ion transfer. Electrospun carbon nanofibers are highly porous and electrically conductive, making them attractive for electrode materials. In this study, free-standing electrodes were prepared by the dip-coating of carbon nanofibers (CNFs) in the MXene (Ti3C2) colloidal solution, which was synthesized via the wet-etching of MAX (Ti3AlC2) phase, and their chemical structures were investigated by X-ray diffraction and Fourier transform infrared spectroscopy. In addition, scanning and transmission electron microscopy were used to investigate the morphological and crystallographic features of MXene-coated CNFs. Surface area and pore volumes were investigated by nitrogen adsorption/desorption measurements. Supercapacitor performance was studied by assembling a 3-electrode system with 1M aqueous sodium sulfate solution as an electrolyte. MXene-coated CNFs exhibited a maximum specific capacitance of 514 F/g at 0.5 A/g, with energy and power densities of 71.4 Wh/kg at 0.5 A/g and 2.3 kW/kg at 5 A/g, respectively, which are relevantly higher compared to the pristine CNFs due to the pseudocapacitive behavior of MXenes. They also showed comparable cyclic stability during 5000 cycles with the CNFs. This result indicates that MXene-coated carbon nanofibers can be effective electrode materials for electrochemical energy storage.

Keywords

• supercapacitors
• pseudocapacitors
• MXene
• polyacrylonitrile
• carbon nanofibers