Acta Crystallographica Section E (Jan 2010)

Aqua(2-oxido-2,2-diphenylacetato-κ2O1,O2)(1,10-phenanthroline-κ2N,N′)copper(II)

  • Xiao-Xia Yang,
  • Fu-Yong Zhang,
  • Shi-Hai Xu

DOI
https://doi.org/10.1107/S1600536809053483
Journal volume & issue
Vol. 66, no. 1
pp. m69 – m69

Abstract

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In the title mononuclear complex, [Cu(C14H10O3)(C12H8N2)(H2O)], the CuII atom is five-coordinated by two N atoms from a 1,10-phenanthroline (phen) ligand, two O atoms from a benzilate ligand and one O atom from a water molecule in a distorted square-pyramidal geometry. The crystal structure is stabilized via intermolecular O—H...O and C—H...O hydrogen bonds, C—H...π interactions and π–π stacking interactions between the pyridine and benzene rings of neighboring phen ligands [centroid–centroid distances = 3.684 (2), 3.564 (2) and 3.380 (1) Å].