Ligand-enabled Ni-catalyzed hydroarylation and hydroalkenylation of internal alkenes with organoborons

Dao-Ming Wang; Li-Qin She; Yichen Wu; Chunyin Zhu; Peng Wang

doi:10.1038/s41467-022-34675-x

Nature Communications (Nov 2022)

Ligand-enabled Ni-catalyzed hydroarylation and hydroalkenylation of internal alkenes with organoborons

Dao-Ming Wang,
Li-Qin She,
Yichen Wu,
Chunyin Zhu,
Peng Wang

Affiliations

Dao-Ming Wang: State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, CAS
Li-Qin She: State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, CAS
Yichen Wu: State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, CAS
Chunyin Zhu: School of Chemistry and Chemical Engineering, Jiangsu University
Peng Wang: State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, CAS

DOI: https://doi.org/10.1038/s41467-022-34675-x
Journal volume & issue: Vol. 13, no. 1
pp. 1 – 8

Abstract

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The hydrocarbofunctionalization of alkenes represents one of the most efficient methods for generating complex products from simple starting materials. Here, the authors report a bulky β-diketone-ligand-enabled hydroarylation and hydroalkenylation of internal alkenes.

Published in Nature Communications

ISSN: 2041-1723 (Online)
Publisher: Nature Portfolio
Country of publisher: United Kingdom
LCC subjects: Science
Website: https://www.nature.com/ncomms/

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