A Zero-Dimensional Organic Lead Bromide of (TPA)<sub>2</sub>PbBr<sub>4</sub> Single Crystal with Bright Blue Emission
Ye Tian,
Qilin Wei,
Hui Peng,
Zongmian Yu,
Shangfei Yao,
Bao Ke,
Qiuyan Li,
Bingsuo Zou
Affiliations
Ye Tian
Beijing Key Laboratory of Nanophotonics & Ultrafine Optoelectronic Systems, Beijing Institute of Technology, Beijing 100081, China
Qilin Wei
Guangxi Key Lab of Processing for Nonferrous Metals and Featured Materials and Key Lab of New Processing Technology for Nonferrous Metals and Materials, Ministry of Education, School of Resources, Environments and Materials, Guangxi University, Nanning 530004, China
Hui Peng
Beijing Key Laboratory of Nanophotonics & Ultrafine Optoelectronic Systems, Beijing Institute of Technology, Beijing 100081, China
Zongmian Yu
Guangxi Key Lab of Processing for Nonferrous Metals and Featured Materials and Key Lab of New Processing Technology for Nonferrous Metals and Materials, Ministry of Education, School of Resources, Environments and Materials, Guangxi University, Nanning 530004, China
Shangfei Yao
Guangxi Key Lab of Processing for Nonferrous Metals and Featured Materials and Key Lab of New Processing Technology for Nonferrous Metals and Materials, Ministry of Education, School of Resources, Environments and Materials, Guangxi University, Nanning 530004, China
Bao Ke
Guangxi Key Lab of Processing for Nonferrous Metals and Featured Materials and Key Lab of New Processing Technology for Nonferrous Metals and Materials, Ministry of Education, School of Resources, Environments and Materials, Guangxi University, Nanning 530004, China
Qiuyan Li
Guangxi Key Lab of Processing for Nonferrous Metals and Featured Materials and Key Lab of New Processing Technology for Nonferrous Metals and Materials, Ministry of Education, School of Resources, Environments and Materials, Guangxi University, Nanning 530004, China
Bingsuo Zou
Guangxi Key Lab of Processing for Nonferrous Metals and Featured Materials and Key Lab of New Processing Technology for Nonferrous Metals and Materials, Ministry of Education, School of Resources, Environments and Materials, Guangxi University, Nanning 530004, China
Blue-luminescence materials are needed in urgency. Recently, zero-dimensional (0D) organic metal halides have attractive much attention due to unique structure and excellent optical properties. However, realizing blue emission with near-UV-visible light excitation in 0D organic metal halides is still a great challenge due to their generally large Stokes shifts. Here, we reported a new (0D) organic metal halides (TPA)2PbBr4 single crystal (TPA+ = tetrapropylammonium cation), in which the isolated [PbBr4]2− tetrahedral clusters are surrounded by organic ligand of TPA+, forming a 0D framework. Upon photoexcitation, (TPA)2PbBr4 exhibits a blue emission peaking at 437 nm with a full width at half-maximum (FWHM) of 50 nm and a relatively small Stokes shift of 53 nm. Combined with density functional theory (DFT) calculations and spectral analysis, it is found that the observed blue emission in (TPA)2PbBr4 comes from the combination of free excitons (FEs) and self-trapped exciton (STE), and a small Stokes shift of this compound are caused by the small structure distortion of [PbBr4]2− cluster in the excited state confined by TPA molecules, in which the multi-phonon effect take action. Our results not only clarify the important role of excited state structure distortion in regulating the STEs formation and emission, but also focus on 0D metal halides with bright blue emission under the near-UV-visible light excitation.
