Improved Synthesis of 1-O-Acyl-β-d-Glucopyranose Tetraacetates

Yu Chen; Huan Lu; Yanyu Chen; Wansheng Yu; Hui Dai; Xianhua Pan

doi:10.3390/molecules22040662

Molecules (Apr 2017)

Improved Synthesis of 1-O-Acyl-β-d-Glucopyranose Tetraacetates

Yu Chen,
Huan Lu,
Yanyu Chen,
Wansheng Yu,
Hui Dai,
Xianhua Pan

Affiliations

Yu Chen: School of Perfume and Aroma Technology, Shanghai Institute of Technology, 100 Haiquan Rd., Shanghai 201418, China
Huan Lu: Shanghai Research Institute of Fragrance and Flavor Industry, 480 Nanning Rd., Shanghai 200232, China
Yanyu Chen: School of Perfume and Aroma Technology, Shanghai Institute of Technology, 100 Haiquan Rd., Shanghai 201418, China
Wansheng Yu: Shanghai Research Institute of Fragrance and Flavor Industry, 480 Nanning Rd., Shanghai 200232, China
Hui Dai: Shanghai Research Institute of Fragrance and Flavor Industry, 480 Nanning Rd., Shanghai 200232, China
Xianhua Pan: School of Perfume and Aroma Technology, Shanghai Institute of Technology, 100 Haiquan Rd., Shanghai 201418, China

DOI: https://doi.org/10.3390/molecules22040662
Journal volume & issue: Vol. 22, no. 4
p. 662

Abstract

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An improved synthesis of 1-O-acyl glucosyl esters that avoids the use of expensive Ag reagents as well as the hydrolysis of unstable glucosyl bromides is reported. Notably, β-configuration products were obtained exclusively in good yields.

Published in Molecules

ISSN: 1420-3049 (Online)
Publisher: MDPI AG
Country of publisher: Switzerland
LCC subjects: Science: Chemistry: Organic chemistry
Website: http://www.mdpi.com/journal/molecules

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