The synthesis and NMR spectral assignments of 3-nitro-4-((6- nitrobenzothiazol-2-yl)amino)-2H-chromen-2-one

Abstract

Complete assignment of the 1H and 13C NMR chemical shifts of new coumarin derivate was described in this paper. A new coumarin derivate was synthesized in good yield by reaction of 4-chloro-3-nitrocoumarin and 6-nitrobenzothiazol-2-amine in ethyl acetate in the presence of triethylamine. The complete spectral assignment was achieved using of 1D (1H and 13C NMR) and 2D (1H-1H-COSY, NOESY, HSQC and HMBC) NMR experiments.

Keywords

• coumarins
• synthesis
• spectral analysis
• 1H NMR
• 13C NMR
• 2D NMR