Divergent regioselective Heck-type reaction of unactivated alkenes and N-fluoro-sulfonamides

Chunyang Zhao; Yang Li; Yujiao Dong; Miao Li; Dan Xia; Shuangqiu Gao; Qian Zhang; Qun Liu; Wei Guan; Junkai Fu

doi:10.1038/s41467-022-33996-1

Nature Communications (Oct 2022)

Divergent regioselective Heck-type reaction of unactivated alkenes and N-fluoro-sulfonamides

Chunyang Zhao,
Yang Li,
Yujiao Dong,
Miao Li,
Dan Xia,
Shuangqiu Gao,
Qian Zhang,
Qun Liu,
Wei Guan,
Junkai Fu

Affiliations

Chunyang Zhao: Jilin Province Key Laboratory of Organic Functional Molecular Design & Synthesis, Department of Chemistry, Northeast Normal University
Yang Li: Jilin Province Key Laboratory of Organic Functional Molecular Design & Synthesis, Department of Chemistry, Northeast Normal University
Yujiao Dong: Institute of Functional Material Chemistry, Department of Chemistry, Northeast Normal University
Miao Li: Jilin Province Key Laboratory of Organic Functional Molecular Design & Synthesis, Department of Chemistry, Northeast Normal University
Dan Xia: Jilin Province Key Laboratory of Organic Functional Molecular Design & Synthesis, Department of Chemistry, Northeast Normal University
Shuangqiu Gao: Jilin Province Key Laboratory of Organic Functional Molecular Design & Synthesis, Department of Chemistry, Northeast Normal University
Qian Zhang: Jilin Province Key Laboratory of Organic Functional Molecular Design & Synthesis, Department of Chemistry, Northeast Normal University
Qun Liu: Jilin Province Key Laboratory of Organic Functional Molecular Design & Synthesis, Department of Chemistry, Northeast Normal University
Wei Guan: Institute of Functional Material Chemistry, Department of Chemistry, Northeast Normal University
Junkai Fu: Jilin Province Key Laboratory of Organic Functional Molecular Design & Synthesis, Department of Chemistry, Northeast Normal University

DOI: https://doi.org/10.1038/s41467-022-33996-1
Journal volume & issue: Vol. 13, no. 1
pp. 1 – 16

Abstract

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The control of regioselectivity in Heck-type reactions of unactivated alkenes is challenging. Here, the authors realize regiodivergent Heck-type reactions of unactivated alkenes and N-fluoro-sulfonamides.

Published in Nature Communications

ISSN: 2041-1723 (Online)
Publisher: Nature Portfolio
Country of publisher: United Kingdom
LCC subjects: Science
Website: https://www.nature.com/ncomms/

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