EPJ Web of Conferences (Jan 2019)

Photodissociation dynamics of nitric oxide from roussin’s red ester probed by time-resolved infrared spectroscopy

  • Yoon Hojeong,
  • Park Seongchul,
  • Lim CheongHa,
  • Lim Manho

DOI
https://doi.org/10.1051/epjconf/201920509020
Journal volume & issue
Vol. 205
p. 09020

Abstract

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To explore nitric oxide (NO)-donating capability of Roussin’s red ester [Fe2(μ-RS)2(NO)4] (RRE), photodissociation of NO from RRE and its subsequent reaction dynamics were probed by monitoring the N–O stretching mode after excitation with a 400-nm photon. As a result of the experiment, the NO generation quantum yield was obtained.