Synthesis and optical properties studies

Abstract

4-(4-Amino-1,5-dimethyl-2-phenyl-1,2-dihydro-pyrazol-3-ylideneamino)-phenol (L1) and 4-(4-Amino-1,5-dimethyl-2-phenyl-1,2-dihydro-pyrazol-3-ylideneamino)-benzoic acid (L2) have been synthesized by the condensation reaction of 4-aminoantipyrine (4-AAP) and 4-aminophenol or 4-aminobenzoic acid in ethanolic solution and are characterized by various physico-chemical techniques. Thin films of L1 and L2 have been prepared by the conventional spin coating technique. X-ray diffraction patterns (XRD) show an amorphous nature for both powder and thin films for L1 and L2 ligands. The optical absorption and refraction properties of L1 and L2 are investigated by spectrophotometric techniques at normal incidence of light in the wavelength range of 200–2500 nm. The absorption spectra show two peaks in the UV region which correspond to π → π∗ transition and a peak in UV–Vis region which may correspond to n → π∗ transition. The values of dispersion parameters Eo, Ed, εL, ε∞ and N/m* are calculated according to the single oscillator model. The presence of the OH group increases the value of ε∞ from 3.21 to 3.32 and the value of N/m* from 7.38 × 1053 to 2.08 × 1054 m−3Kg−1. The optical band transition is found to be indirect allowing fundamental energy gap values of 3.4 and 3.9 eV and onset energy gap values of 2.1 and 2.6 eV for L1 and L2, respectively.

Keywords

• 4-Aminoantipyrine
• Optical properties
• Thin films