Molecules (Aug 2005)

Synthesis of Cyclophellitol Utilizing a Palladium Chloride Mediated-Ferrier-II Rearrangement

  • S. Ikegami,
  • H. Takahashi

DOI
https://doi.org/10.3390/10080901
Journal volume & issue
Vol. 10, no. 8
pp. 901 – 911

Abstract

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Cyclophellitol and its C3-epimer have been synthesized from5-enoglucopyranoside and 5-enomannopyranoside, respectively. The carbocyclic skeletonwas constructed through a Ferrier-II reaction meditated by PdCl2.

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