IUCrData (Apr 2019)

The crystal structure of 2-[(tert-butyldiphenylsilyl)oxy]-1,2-diphenylethan-1-one

  • Martin J. Di Grandi,
  • Brett Taylor,
  • Peter W. R. Corfield

DOI
https://doi.org/10.1107/s2414314619004784
Journal volume & issue
Vol. 4, no. 4
p. x190478

Abstract

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The title compound, C30H30O2Si, was synthesized and structurally characterized in order to determine the influence of the bulky silyl protecting group on the conformation of the benzoin moiety, with a view to directing the stereochemistry of the borohydride reduction of the benzoin. The crystal structure shows a benzoin O—C—C—O torsion angle of 38.34 (1)°, not greatly different from that found in benzoin itself. In the crystal, a weak C—H...O hydrogen bond between the carbonyl group and a phenyl H atom of a symmetry-related molecule forms chains along [100].

Keywords