Nanomaterials (Oct 2022)

Synthesis and HRTEM Investigation of EuRbFe<sub>4</sub>As<sub>4</sub> Superconductor

  • Alena Yu. Degtyarenko,
  • Igor A. Karateev,
  • Alexey V. Ovcharov,
  • Vladimir A. Vlasenko,
  • Kirill S. Pervakov

DOI
https://doi.org/10.3390/nano12213801
Journal volume & issue
Vol. 12, no. 21
p. 3801

Abstract

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In the stoichiometric iron-based superconductor EuRbFe4As4, superconductivity coexists with a long-range magnetic ordering in Eu layers. Using high-resolution transmission electron microscopy (HRTEM), we observed an atomic structure of as-grown EuRbFe4As4 crystals. HRTEM shows that crystals have two-dimensional intrinsic nanoinclusions established to be the RbFe2As2 (122) phase with a volume fraction of ~5.6%. In contrast with the CaKFe4As4 compound, similar inclusions are not superconducting down to 2 K, and no second magnetization peak was observed in the magnetization measurements at low temperature with B ‖ ab. We show that the non-superconducting 122 phase nanoinclusions could act as 2D pinning centers.

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