Development of Quantum Dot (QD) Based Color Converters for Multicolor Display
Muhammad T. Sajjad,
Ashu K. Bansal,
Francesco Antolini,
Eduard Preis,
Lenuta Stroea,
Stefano Toffanin,
Michele Muccini,
Luca Ortolani,
Andrea Migliori,
Sybille Allard,
Ullrich Scherf,
Ifor D. W. Samuel
Affiliations
Muhammad T. Sajjad
Organic Semiconductor Centre, SUPA, School of Physics and Astronomy, University of St Andrews, North Haugh, St Andrews KY16 9SS, UK
Ashu K. Bansal
Organic Semiconductor Centre, SUPA, School of Physics and Astronomy, University of St Andrews, North Haugh, St Andrews KY16 9SS, UK
Francesco Antolini
Photonics Micro and Nanostructures Laboratory, ENEA Frascati, Fusion and Technologies for Nuclear Safety and Security Department, Physical Technologies for Safety and Health Division, Via E. Fermi 45, 00044 Frascati, Italy
Eduard Preis
Center for Smart Materials & Systems, Bergische Universität Wuppertal, Gauss-Strasse 20, 42119 Wuppertal, Germany
Lenuta Stroea
Petru Poni Institute of Macromolecular Chemistry Gr. Ghica Voda Alley, 41 A, 700487 Iasi, Romania
Stefano Toffanin
Istituto per lo Studio dei Materiali Nanostrutturati (ISMN), Consiglio Nazionale delle Ricerche (CNR), Via P. Gobetti, 101, 40129 Bologna, Italy
Michele Muccini
Istituto per lo Studio dei Materiali Nanostrutturati (ISMN), Consiglio Nazionale delle Ricerche (CNR), Via P. Gobetti, 101, 40129 Bologna, Italy
Luca Ortolani
Institute for Microelectronics and Microsystems, Consiglio Nazionale delle Ricerche (CNR), Via Gobetti 101, 40129 Bologna, Italy
Andrea Migliori
Institute for Microelectronics and Microsystems, Consiglio Nazionale delle Ricerche (CNR), Via Gobetti 101, 40129 Bologna, Italy
Sybille Allard
Center for Smart Materials & Systems, Bergische Universität Wuppertal, Gauss-Strasse 20, 42119 Wuppertal, Germany
Ullrich Scherf
Center for Smart Materials & Systems, Bergische Universität Wuppertal, Gauss-Strasse 20, 42119 Wuppertal, Germany
Ifor D. W. Samuel
Organic Semiconductor Centre, SUPA, School of Physics and Astronomy, University of St Andrews, North Haugh, St Andrews KY16 9SS, UK
Many displays involve the use of color conversion layers. QDs are attractive candidates as color converters because of their easy processability, tuneable optical properties, high photoluminescence quantum yield, and good stability. Here, we show that emissive QDs with narrow emission range can be made in-situ in a polymer matrix, with properties useful for color conversion. This was achieved by blending the blue-emitting pyridine based polymer with a cadmium selenide precursor and baking their films at different temperatures. To achieve efficient color conversion, blend ratio and baking temperature/time were varied. We found that thermal decomposition of the precursor leads to highly emissive QDs whose final size and emission can be controlled using baking temperature/time. The formation of the QDs inside the polymer matrix was confirmed through morphological studies using atomic force microscopy (AFM) and transmission electron microscopy (TEM). Hence, our approach provides a cost-effective route to making highly emissive color converters for multi-color displays.