Removal of microplastics from aqueous media using activated jute stick charcoal

Abstract

Microplastics (MPs), which are repositories of various pollutants, have significant effects on the people and the environment. Therefore, there is an urgent need for efficient and eco-friendly techniques to eliminate microplastics from water-based environments. This study introduces a new method for producing jute stick-activated charcoal (JSAC) by placing jute sticks on high-temperature pyrolysis without oxygen, followed by chemical activation with HCl. This process greatly enhances the adsorption capacity of JSAC for polyvinylchloride-based microplastics (PVC-MPs). JSAC was characterized using UV–Vis, FT-IR, XRD, and SEM studies both before and after adsorption. The study investigated the influence of pH, adsorbent quantity, and contact time on the optimization of the JSAC process. The PVC-MPs exhibited a maximum adsorption capacity of 94.12 % for the target MPs (5 g L−1) within 120 min when 10 g L−1 of JSAC was added at pH 7.This work also examined adsorption rate and various isotherm models. Adsorption kinetics analysis reveals electrostatic, hydrogen bond, π-π, and hydrophobic interactions are the combined forces responsible for MPs adsorption onto JSAC. However, the decrease in hydrophobicity in acidic or basic media led to a decrease in adsorption. The isotherm analysis was conducted using the Langmuir isotherm model, and predicted the maximum adsorption capacity of PVC-MPs to be 4.4668 mg/g. Furthermore, by employing density functional theory, the interaction energy after PVC-MP adsorption was calculated to be −269 kcal/mol, demonstrating robust adsorption and agreement with the experimental findings. Due to its large surface area and porous structure containing many functional groups, JSAC can potentially be used to treat MP contamination in water.

Keywords

• Adsorption
• Density functional theory
• Kinetics
• Isotherm and PVC microplastics