Energies (Sep 2021)

A Review: Ion Transport of Two-Dimensional Materials in Novel Technologies from Macro to Nanoscopic Perspectives

  • Nawapong Unsuree,
  • Sorasak Phanphak,
  • Pongthep Prajongtat,
  • Aritsa Bunpheng,
  • Kulpavee Jitapunkul,
  • Pornpis Kongputhon,
  • Pannaree Srinoi,
  • Pawin Iamprasertkun,
  • Wisit Hirunpinyopas

DOI
https://doi.org/10.3390/en14185819
Journal volume & issue
Vol. 14, no. 18
p. 5819

Abstract

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Ion transport is a significant concept that underlies a variety of technologies including membrane technology, energy storages, optical, chemical, and biological sensors and ion-mobility exploration techniques. These applications are based on the concepts of capacitance and ion transport, so a prior understanding of capacitance and ion transport phenomena is crucial. In this review, the principles of capacitance and ion transport are described from a theoretical and practical point of view. The review covers the concepts of Helmholtz capacitance, diffuse layer capacitance and space charge capacitance, which is also referred to as quantum capacitance in low-dimensional materials. These concepts are attributed to applications in the electrochemical technologies such as energy storage and excitable ion sieving in membranes. This review also focuses on the characteristic role of channel heights (from micrometer to angstrom scales) in ion transport. Ion transport technologies can also be used in newer applications including biological sensors and multifunctional microsupercapacitors. This review improves our understanding of ion transport phenomena and demonstrates various applications that is applicable of the continued development in the technologies described.

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