AIP Advances (Dec 2011)

Martensite-like transition and spin-glass behavior in nanocrystalline Pr0.5Ca0.5MnO3

  • S. Narayana Jammalamadaka,
  • S. S. Rao,
  • J. Vanacken,
  • A. Stesmans,
  • S. V. Bhat,
  • V. V. Moshchalkov

DOI
https://doi.org/10.1063/1.3664786
Journal volume & issue
Vol. 1, no. 4
pp. 042151 – 042151-9

Abstract

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We report on isothermal pulsed (20 ms) field magnetization, temperature dependent AC – susceptibility, and the static low magnetic field measurements carried out on 10 nm sized Pr0.5Ca0.5MnO3 nanoparticles (PCMO10). The saturation field for the magnetization of PCMO10 (∼ 250 kOe) is found to be reduced in comparison with that of bulk PCMO (∼300 kOe). With increasing temperature, the critical magnetic field required to ‘melt’ the residual charge-ordered phase decays exponentially while the field transition range broadens, which is indicative of a Martensite-like transition. The AC - susceptibility data indicate the presence of a frequency-dependent freezing temperature, satisfying the conventional Vogel-Fulcher and power laws, pointing to the existence of a spin-glass-like disordered magnetic phase. The present results lead to a better understanding of manganite physics and might prove helpful for practical applications.