Acta Crystallographica Section E (Jul 2013)

catena-Poly[(diaquacadmium)-μ-iminodiacetato-κ4O,N,O′:O′′]

  • Gang-Hong Pan,
  • Jin-Niu Tang,
  • Zhong-Jing Huang,
  • Yi-Fan Liao,
  • Bo-Fa Mo

DOI
https://doi.org/10.1107/S1600536813017121
Journal volume & issue
Vol. 69, no. 7
pp. m416 – m416

Abstract

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In the title compound, [Cd(C4H5NO4)(H2O)2]n, the CdII atom exhibits a distorted octahedral coordination geometry, defined by one N atom and three O atoms from two iminodiacetate (IDA) ligands and two water molecules. The tridentate IDA ligand additionally bridges via one of its carboxylate O atoms to another CdII atom, thus forming a zigzag chain along [001]. A three-dimensional network is completed by intermolecular O—H...O and N—H...O hydrogen bonds.