Electrodeposited PPy@TiO₂ and PEDOT@TiO₂ Counter Electrodes for [Co(bpy)₃]^2+/3+ Redox Mediator-Based Dye-Sensitized Solar Cells

Abstract

The main goal of this work is to enhance the catalytic performance of PPy and PEDOT films toward the Co2+/Co3+ redox couple. PPy and PEDOT films were electrodeposited separately on a porous TiO2 template to assess their suitability as alternative catalysts in dye-sensitized solar cells (DSSC) based on the [Co(bpy)3]2+/3+ redox shuttle. The obtained PPy@TiO2 and PEDOT@TiO2 counter electrodes displayed much rougher surfaces. Electrochemical studies indicate the superior catalytic activity of both the electrodeposited electrodes toward Co3+ reduction, as indicated by lower charge transfer resistance than that of pristine films and even that of Pt electrodes. Therefore, the fabricated DSSC devices with these counter electrodes achieved higher power conversion efficiencies compared to cells with pristine PPy and PEDOT counter electrodes, or even with a Pt counter electrode. Interestingly, the assembled DSSC device with a PEDOT@TiO2 counter electrode displayed the highest performance among all with a power conversion efficiency of 6.62%, which is better than that obtained by the device with a Pt electrode (6.07%).

Keywords

• dye-sensitized solar cells
• counter electrodes
• copper polypyridyl redox shuttle
• conductive polymers
• electrochemical deposition