Electrochemical Impedance Spectrum (EIS) Variation of Lithium-Ion Batteries Due to Resting Times in the Charging Processes

Abstract

The electrochemical impedance spectrum (EIS) is a non-destructive technique for the on-line evaluation and monitoring of the performance of lithium-ion batteries. However, the measured EIS can be unstable and inaccurate without the proper resting time. Therefore, we conducted comprehensive EIS tests during the charging process and at different state of charge (SOC) levels with various resting times. The test results revealed two findings: (1) EIS tests with a constant long resting time showed a clear pattern in the impedance spectral radius—a decrease followed by a slight increase. We analyzed the impedance data using an equivalent circuit model and explained the changes through circuit parameters. (2) We examined the effect of resting time on impedance at consistent SOC levels. While low SOC levels exhibited significant sensitivity to resting time, medium SOC levels showed less sensitivity, and high SOC levels had minimal impact on resting time. The equivalent circuit parameters matched the observed trends. Kramers–Kronig transformation was conducted to assess the reliability of the experiments. This study not only summarizes the relationship between the EIS and SOC but also highlights the importance of resting time in impedance analysis. Recognizing the role of the resting time could enhance impedance-based battery studies, contribute to refined battery status evaluation, and help researchers to design proper test protocols.

Keywords

• electrochemical impedance spectrum
• resting-time
• state of charge
• equivalent circuit model