Recent Progress in Plasmonic Hybrid Photocatalysis for CO₂ Photoreduction and C–C Coupling Reactions

Abstract

Plasmonic hybrid nanostructures have been investigated as attractive heterogeneous photocatalysts that can utilize sunlight to produce valuable chemicals. In particular, the efficient photoconversion of CO2 into a stable hydrocarbon with sunlight can be a promising strategy to achieve a sustainable human life on Earth. The next step for hydrocarbons once obtained from CO2 is the carbon–carbon coupling reactions to produce a valuable chemical for energy storage or fine chemicals. For these purposes, plasmonic nanomaterials have been widely investigated as a visible-light-induced photocatalyst to achieve increased efficiency of photochemical reactions with sunlight. In this review, we discuss recent achievements involving plasmonic hybrid photocatalysts that have been investigated for CO and CO2 photoreductions to form multi-carbon products and for C–C coupling reactions, such as the Suzuki–Miyaura coupling reactions.

Keywords

• plasmonic nano-catalysts
• photocatalytic reaction
• CO₂ reductions
• C–C cross-coupling