Textured Asymmetric Membrane Electrode Assemblies of Piezoelectric Phosphorene and Ti3C2Tx MXene Heterostructures for Enhanced Electrochemical Stability and Kinetics in LIBs

Yihui Li; Juan Xie; Ruofei Wang; Shugang Min; Zewen Xu; Yangjian Ding; Pengcheng Su; Xingmin Zhang; Liyu Wei; Jing-Feng Li; Zhaoqiang Chu; Jingyu Sun; Cheng Huang

doi:10.1007/s40820-023-01265-5

Nano-Micro Letters (Jan 2024)

Textured Asymmetric Membrane Electrode Assemblies of Piezoelectric Phosphorene and Ti3C2Tx MXene Heterostructures for Enhanced Electrochemical Stability and Kinetics in LIBs

Yihui Li,
Juan Xie,
Ruofei Wang,
Shugang Min,
Zewen Xu,
Yangjian Ding,
Pengcheng Su,
Xingmin Zhang,
Liyu Wei,
Jing-Feng Li,
Zhaoqiang Chu,
Jingyu Sun,
Cheng Huang

Affiliations

Yihui Li: Volta and DiPole Materials Labs, College of Energy, Soochow Institute for Energy and Materials InnovationS (SIEMIS), Key Laboratory of Advanced Carbon Materials and Wearable Energy Technologies of Jiangsu Province, Key Laboratory of Core Technology of High Specific Energy Battery and Key Materials for Petroleum and Chemical Industry, Soochow University
Juan Xie: School of Materials Science and Engineering, Jiangsu University
Ruofei Wang: College of Underwater Acoustic Engineering, Harbin Engineering University
Shugang Min: College of Underwater Acoustic Engineering, Harbin Engineering University
Zewen Xu: Volta and DiPole Materials Labs, College of Energy, Soochow Institute for Energy and Materials InnovationS (SIEMIS), Key Laboratory of Advanced Carbon Materials and Wearable Energy Technologies of Jiangsu Province, Key Laboratory of Core Technology of High Specific Energy Battery and Key Materials for Petroleum and Chemical Industry, Soochow University
Yangjian Ding: Volta and DiPole Materials Labs, College of Energy, Soochow Institute for Energy and Materials InnovationS (SIEMIS), Key Laboratory of Advanced Carbon Materials and Wearable Energy Technologies of Jiangsu Province, Key Laboratory of Core Technology of High Specific Energy Battery and Key Materials for Petroleum and Chemical Industry, Soochow University
Pengcheng Su: Volta and DiPole Materials Labs, College of Energy, Soochow Institute for Energy and Materials InnovationS (SIEMIS), Key Laboratory of Advanced Carbon Materials and Wearable Energy Technologies of Jiangsu Province, Key Laboratory of Core Technology of High Specific Energy Battery and Key Materials for Petroleum and Chemical Industry, Soochow University
Xingmin Zhang: Shanghai Synchrotron Radiation Facility, Shanghai Advanced Research Institute, Shanghai Institute of Applied Physics, Chinese Academy of Sciences
Liyu Wei: State Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University
Jing-Feng Li: State Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University
Zhaoqiang Chu: College of Underwater Acoustic Engineering, Harbin Engineering University
Jingyu Sun: Volta and DiPole Materials Labs, College of Energy, Soochow Institute for Energy and Materials InnovationS (SIEMIS), Key Laboratory of Advanced Carbon Materials and Wearable Energy Technologies of Jiangsu Province, Key Laboratory of Core Technology of High Specific Energy Battery and Key Materials for Petroleum and Chemical Industry, Soochow University
Cheng Huang: Volta and DiPole Materials Labs, College of Energy, Soochow Institute for Energy and Materials InnovationS (SIEMIS), Key Laboratory of Advanced Carbon Materials and Wearable Energy Technologies of Jiangsu Province, Key Laboratory of Core Technology of High Specific Energy Battery and Key Materials for Petroleum and Chemical Industry, Soochow University

DOI: https://doi.org/10.1007/s40820-023-01265-5
Journal volume & issue: Vol. 16, no. 1
pp. 1 – 21

Abstract

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Highlights An asymmetric membrane electrode based on phosphorene/MXene heterostructure-textured nanopiezocomposite was fabricated via a polar urea-assisted self-assembly strategy and additive manufacturing of the heterostructure beyond the skin effect. The merits of this novel asymmetric heterostructure-textured electrode and its intrinsic piezoelectricity were detailedly discussed. The stepwise lithiation process of phosphorene was revealed, and the enhanced electrochemical properties of this phosphorene-based nanopiezocomposite textured electrode were verified by the improved cycling stability and kinetics.

Published in Nano-Micro Letters

ISSN: 2311-6706 (Print); 2150-5551 (Online)
Publisher: SpringerOpen
Country of publisher: Germany
LCC subjects: Technology
Website: http://www.springer.com/40820

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