Acta Crystallographica Section E (Sep 2010)

1,3-Bis(2,6-diisopropylphenyl)imidazolidin-2-ylidene

  • Nick A. Giffin,
  • Arthur D. Hendsbee,
  • Jason D. Masuda

DOI
https://doi.org/10.1107/S1600536810029922
Journal volume & issue
Vol. 66, no. 9
pp. o2194 – o2194

Abstract

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The title compound, C27H38N2, is the first reported free imidazolidin-2-ylidene carbene with 2,6-diisopropylphenyl groups in the 1,3-positions. The five-membered ring adopts a twisted conformation and the dihedral angle between the aromatic rings is 48.81 (6)°. Both isopropyl groups attached to one of the benzene rings are disordered over two sets of sites in 0.74 (2):0.26 (2) and 0.599 (8):0.401 (8) ratios.