Journal of Materials Research and Technology (May 2024)

A convolutional neural network -VGG16 method for corrosion inhibition of 304SS in sulfuric acid solution by timoho leaf extract

  • Femiana Gapsari,
  • Fitri Utaminingrum,
  • Chin Wei Lai,
  • Khairul Anam,
  • Abdul M. Sulaiman,
  • Muhamad F. Haidar,
  • Tobias S. Julian,
  • Eno E. Ebenso

Journal volume & issue
Vol. 30
pp. 1116 – 1127

Abstract

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A corrosion inhibition test, coupled with a quantification of in-situ H2 evolution, can be used to evaluate an organic inhibitor such as Timoho leaf extract (TLE). TLE is a biodegradable and effective corrosion inhibitor because of its potential to protect 304SS against sulfuric acid. TLE corrosion inhibitor was studied through systematic electrochemical experiments and morphological characterization, with a concentration range of 0–6g L−1. Convolutional Neural Network (CNN)-VGG16 was one of the machine learning approaches used to classify and predict physical changes in hydrogen gas bubbles. Constituents of the TLE and 304SS surfaces were analyzed by FT-IR and UV–Vis tests. The results suggested that 3 g L−1 TLE inhibitor was able to reduce the corrosion rate by 99.37 %. The TLE's inhibition mechanism on 304SS was mixed adsorption and mixed type inhibitor that followed the Isothermal Freundlich Equation. The prediction model by CNN-VGG16 for corrosion tests at varied inhibitor doses was 96% accurate. SEM tests revealed that TLE constituent adsorption on the 304SS surface had a smooth surface morphology with few degraded spots.

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