A new sodium dimangnesium trivanadate, NaMg2V3O10

Abstract

A single crystal of NaMg2V3O10 has been prepared by solid-state reaction at 1173 K. The [Mg2(V3O10)]− anions are built up from edge-sharing MgO6 octahedra to form [Mg4O18] units, which are linked to each other by trivanadate groups (V3O10). The Na+ ions are located in the tunnel space.