Reactions (Mar 2023)

UV/VIS-Spectroscopic Inline Measurement for the Detection of Fouling Processes during the Polymerization of N-Vinylpyrrolidone

  • Erik Spoor,
  • Stefan Welzel,
  • Ulrich Nieken,
  • Matthias Rädle

DOI
https://doi.org/10.3390/reactions4010011
Journal volume & issue
Vol. 4, no. 1
pp. 176 – 188

Abstract

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With the goal to better process the monitoring of occurring fouling, a backscatter probe was developed to perform in-line measurements in a half-shell reactor during the reaction of N-vinylpyrrolidone (NVP) to polyvinylpyrrolidone (PVP). The measurement technique detects the changes of bands in the UV range, which allows a direct correlation with the concentration. Thus, the measured absorbance signal allows a conclusion on the accumulation of fouling in the reactor and on changes in the conversion at the measurement location.

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