Hydrothermal Synthesis of MnO₂/Reduced Graphene Oxide Composite for 4-Nitrophenol Sensing Applications

Abstract

Recently, the electrochemical sensing approach has attracted materials/electrochemical scientists to design and develop electrode materials for the construction of electrochemical sensors for the detection of para-nitrophenol (4-NP). In the present study, we have prepared a hybrid composite of MnO2 and rGO (MnO2/rGO) using a hydrothermal approach. The morphological features of the prepared MnO2/rGO composite were studied by scanning electron microscopy, whereas the phase purity and formation of the MnO2/rGO composite were authenticated via the powder X-ray diffraction method. Energy-dispersive X-ray spectroscopy was also employed to analyze the elemental composition of the prepared MnO2/rGO composite. In further studies, a glassy carbon electrode (GCE) was modified with MnO2/rGO composite (MnO2/rGO/GCE) and explored as 4-nitrophenol (4-NP) sensor. The fabricated MnO2/rGO/GCE exhibited a reasonably good limit of detection of 0.09 µM with a sensitivity of 0.657 µA/µMcm2. The MnO2/rGO/GCE also demonstrates good selectivity, stability and repeatability in 50 cycles.

Keywords

• MnO₂/rGO composite
• 4-NP
• cyclic voltammetry
• electrochemical sensor